Thursday, June 14, 2012

Where does oil and methane come from?

Rush was pointing out today that there is oil in the Middle East, which is desert and couldn't have had dinosaurs, and no dinosaurs in Africa which would be just the terrain they'd like.

He apparently doesn't know that the climate today is Vaaaaastly different than what it was millions of years ago. Kansas, for example, was under water millions of years ago. So was Egypt.

Anyway,  how can there be methane on Titan without any dinosaurs, was a caller's question.

Methane  is a chemical compound with the chemical formula CH4. It is the simplest alkane, the main component of natural gas, and probably the most abundant organic compound on earth. The relative abundance of methane makes it an attractive fuel. However, because it is a gas at normal conditions, methane is difficult to transport from its source.

Methane is a relatively potent greenhouse gas. The concentration of methane in the Earth's atmosphere in 1998, expressed as a mole fraction, was 1745 nmol/mol (parts per billion, ppb), up from 700 nmol/mol in 1750. By 2008, however, global methane levels, which had stayed mostly flat since 1998, had risen to 1800 nmol/mo

Methane was discovered and isolated by Alessandro Volta between 1776 and 1778 when studying marsh gas from Lake Maggiore. It is the major component of natural gas, about 87% by volume. The major source of methane is extraction from geological deposits known as natural gas fields, with coal seam gas extraction becoming a major source (see Coal bed methane extraction, a method for extracting methane from a coal deposit, while enhanced coal bed methane recovery is a method of recovering methane from an non-mineable coal seams). It is associated with other hydrocarbon fuels, and sometimes accompanied by helium and nitrogen. The gas at shallow levels (low pressure) forms by anaerobic decay of organic matter and reworked methane from deep under the Earth's surface. In general, sediments buried deeper and at higher temperatures than those that contain oil generate natural gas.
It is generally transported in bulk by pipeline in its natural gas form, or LNG carriers in its liquefied form; few countries transport it by truck.

Alternative sources

Apart from gas fields, an alternative method of obtaining methane is via biogas generated by the fermentation of organic matter including manure, wastewater sludge, municipal solid waste (including landfills), or any other biodegradable feedstock, under anaerobic conditions. Rice fields also generate large amounts of methane during plant growth. Methane hydrates/clathrates (ice-like combinations of methane and water on the sea floor, found in vast quantities) are a potential future source of methane. Cattle belch methane accounts for 16% of the world's annual methane emissions to the atmosphere.[One study reported that the livestock sector in general (primarily cattle, chickens, and pigs) produces 37% of all human-induced methane.[ Early research has found a number of medical treatments and dietary adjustments that help slightly limit the production of methane in ruminants.[ A more recent study, in 2009, found that at a conservative estimate, at least 51% of global greenhouse gas emissions were attributable to the life cycle and supply chain of livestock products, meaning all meat, dairy, and by-products, and their transportation


Methane is created near the Earth's surface, primarily by microorganisms by the process of methanogenesis. It is carried into the stratosphere by rising air in the tropics. Uncontrolled build-up of methane in the atmosphere is naturally checked — although human influence can upset this natural regulation — by methane's reaction with hydroxyl radicals formed from singlet oxygen atoms and with water vapor. It has a net lifetime of about 10 years, and is primarily removed by conversion to carbon dioxide and water
Methane also affects the degradation of the ozone layer.





In addition, there is a large (but unknown) amount of methane in methane clathrates in the ocean floors as well as the Earth's crust. Most methane is the result of biological process called methanogenesis.
In 2010, methane levels in the Arctic were measured at 1850 nmol/mol, a level over twice as high as at any time in the previous 400,000 years. Historically, methane concentrations in the world's atmosphere have ranged between 300 and 400 nmol/mol during glacial periods commonly known as ice ages, and between 600 to 700 nmol/mol during the warm interglacial periods. It has a high global warming potential: 72 times that of carbon dioxide over 20 years, and 25 times over 100 years, and the levels are rising.

Methane in the Earth's atmosphere is an important greenhouse gas with a global warming potential of 25 compared to CO2 over a 100-year period (although accepted figures probably represents an underestimate). This means that a methane emission will have 25 times the effect on temperature of a carbon dioxide emission of the same mass over the following 100 years. Methane has a large effect for a brief period (a net lifetime of 8.4 years in the atmosphere), whereas carbon dioxide has a small effect for a long period (over 100 years). Because of this difference in effect and time period, the global warming potential of methane over a 20 year time period is 72. The Earth's atmospheric methane concentration has increased by about 150% since 1750, and it accounts for 20% of the total radiative forcing from all of the long-lived and globally mixed greenhouse gases (these gases don't include water vapor which is by far the largest component of the greenhouse effect). Usually, excess methane from landfills and other natural producers of methane is burned so CO2 is released into the atmosphere instead of methane, because methane is a more effective greenhouse gas. Recently, methane emitted from coal mines has been successfully utilized to generate electricity.


Titan (or Saturn VI) is the largest moon of Saturn. It is the only natural satellite known to have a dense atmosphere,and the only object other than Earth for which clear evidence of stable bodies of surface liquid has been found.


Titan is the sixth ellipsoidal moon from Saturn. Frequently described as a planet-like moon, Titan has a diameter roughly 50% larger than Earth's moon and is 80% more massive. It is the second-largest moon in the Solar System, after Jupiter's moon Ganymede, and it is larger by volume than the smallest planet, Mercury, although only half as massive. Titan was the first known moon of Saturn, discovered in 1655 by the Dutch astronomer Christiaan Huygens, and was the fifth moon of a planet apart from the Earth to be discovered.
Titan is primarily composed of water ice and rocky material. Much as with Venus prior to the Space Age, the dense, opaque atmosphere prevented understanding of Titan's surface until new information accumulated with the arrival of the Cassini–Huygens mission in 2004, including the discovery of liquid hydrocarbon lakes in the satellite's polar regions. The surface is geologically young; although mountains and several possible cryovolcanoes have been discovered, it is smooth and few impact craters have been found.
The atmosphere of Titan is largely composed of nitrogen; minor components lead to the formation of methane and ethane clouds and nitrogen-rich organic smog. The climate—including wind and rain—creates surface features similar to those of Earth, such as sand dunes, rivers, lakes and seas (probably of liquid methane and ethane), and deltas, and is dominated by seasonal weather patterns as on Earth. With its liquids (both surface and subsurface) and robust nitrogen atmosphere, Titan's methane cycle is viewed as an analog to Earth's water cycle, although at a much lower temperature.

The satellite is thought as a possible host for microbial extraterrestrial life or, at least, as a prebiotic environment rich in complex organic chemistry with a possible subsurface liquid ocean serving as a biotic environment.



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